Title:

Influence of the second shell layer (TOPO, HDA) on the optical properties of CdSe/ZnS nanocrystal powder

Group publication title:

Optica Applicata

Creator:

Zatryb, G. ; Podhorodecki, A. ; Misiewicz, J. ; Nauka, K.

Contributor:

Gaj, Miron. Redakcja

Subject and Keywords:

optyka ; nanocrystals ; photoluminescence ; CdSe/ZnS ; HDA ; TOPO

Description:

Optica Applicata, Vol. 37, 2007, nr 4, s. 459-464

Abstrakt:

CdSe/ZnS nanocrystal powder covered with an additional cap layer (II-shell) of hexadecylamine (HDA) or tri-n-octylphosphine oxide (TOPO) has been investigated by using photoluminescence (PL) and total photoluminescence excitation (TPLE) spectroscopy. Depending on II-shell composition, different emission properties of the system have been observed. Strong emission bands at 2.00 eV and 1.95 eV related to nanocrystalline CdSe core recombination have been observed for TOPO and HDA-CdSe/ZnS nanocrystals, respectively. In both cases, weak emission bands centered at 3.5 and 2.8 eV have also been found. Moreover, in the case of TOPO II-shell, emission band at 1.65 eV related to defect state recombination has been observed. In both cases, similar absorption properties have been found, indicating that II-shell composition does not change nanocrystal absorption properties in an efficient way.

Publisher:

Oficyna Wydawnicza Politechniki Wrocławskiej

Place of publication:

Wrocław

Date:

2007

Resource Type:

artykuł

Source:

<sygn. PWr A3481II> ; click here to follow the link ; click here to follow the link

Language:

eng

Relation:

Optica Applicata ; Optica Applicata, Vol. 37, 2007 ; Optica Applicata, Vol. 37, 2007, nr 4 ; Politechnika Wrocławska. Wydział Podstawowych Problemów Techniki

Rights:

Wszystkie prawa zastrzeżone (Copyright)

Access Rights:

Dla wszystkich w zakresie dozwolonego użytku

Location:

Politechnika Wrocławska